I don't think any birth control is 100% effective (other than abstinence) so it's possible to still get pregnant.
I don't know about the time thing, I think as long as you take it every day that it should still work. Judging by your title, it sounds like you do take it the same time every day, so you shouldn't have to worry about that.
Birth Control also can mess with your system too, maybe you're just late or something. I missed entire periods twice when I was on birth control. If you think you might be pregnant, schedule an appt with your doc.