First of all, how regular are her menstrual pattern?
Yes, it is always possible for her to be pregnant if sperm enters the vagina. Right after menses is a bit less likely, both because typically (bot not always) ovulation is still some days off.
Note that sperm typically live around 5 days, and as such, pregnancy is more likely from 5 days before ovulation.
But you can't really be sure until you wait a couple of weeks and then have a pregnancy test.