When you are ovulating......If you can sense when it happens, otherwise you'll be taking your temp all the time. For me, (i'm 34) I realised I was ovulationg, there was increased clear jelled stuff coming out of you-know-where. Anyway I put the moves on my husband, and bam! Baby :)
also it helps to be in a stable relationship, with decent housing......A good income with some sort of health insurance. A no-brainer, but you'd be suprised how many don't consider these basic issues.
My accountant is 46 and has a 8 month old. She's had cancer, and was told she would never conceive. Suprise, she did and the "miracle baby" is totally healthy. She was on bed rest for 4 months, towards the end. Also she gained 90 pounds! Something to consider. Good luck!